MATERIAL SAFETY DATA SHEET

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PRODUCT NAME: 844-5558 Pthalo Green Paste

HMIS CODES: H F R P

PRODUCT CODE: 99-2 2 3 0 J

================== SECTION I - MANUFACTURER IDENTIFICATION =================

MANUFACTURER'S NAME: Pruett-Schaffer Chemical Co.

ADDRESS: 3327 Stafford Street Pittsburgh PA 15204

EMERGENCY PHONE: 1-800-633-8253 INFORMATION PHONE: 1-412-771-2000

REVISION DATE: 09/27/04 NAME OF PREPARER: Robert P. Barry

========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========

VAPOR PRESSURE WEIGHT

REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP Deg F PERCENT

----------------------------------------------------------------------------------------------------

Film Forming Resin Not Avail. 24.20

Green Pigment, inert 1328-53-6 0 0 19.00

ACGIH TLV: 10 mg/m3

* Methyl Isobutyl Ketone, 4-Methyl-2-pentanone108-10-1 15 68 16.00

ACGIH TWA8 TLV: 50ppm or 205 mg/m3, 75ppm STEL. OSHA TWA8 PEL 100ppm mg/m3.

OSHA: 50ppm TWA8, 205 mg/m3 TWA8, 75ppm STEL, 300 mg/m3 STEL.

n-Butyl Acetate (butyl ethanoate) 123-86-4 8 68 14.00

ACGIH TLV: 150ppm TWA, 200ppm STEL. OSHA PEL: 150ppm TWA.

* Xylenes, (o-, m-, & p-dimethyl benzene isomer mix)1330-20-7 25 77 12.43

OSHA PEL: 100ppm TWA, 150ppm TWA STEL. ACGIH TLV: 100ppm TWA, 150ppm STEL.

Petroleum Solvent 64742-94-5 .15 77 8.82

ACGIH TLV: 5mg/m3, OSHA PEL: 5mg/m3, Other TLV: (mist)

* Trimethylbenzene 95-63-6 0 0 4.90

ACGIH TLV: 25 ppm TWA. OSHA PEL: 25 ppm TWA.

* Ethyl Benzene 100-41-4 0 0 0.44

OSHA: 100ppm TWA, 125ppm TWA STEL

* Cumene 98-82-8 0 0 0.21

ACGIH TLV: 50 ppm (S). OSHA PEL: 50 ppm (S).

* Indicates toxic chemical(s) subject to the reporting requirements of section

313 of Title III and of 40 CFR 372.

LEGEND: (C)=Ceiling limit; (S)=Skinlimit; (STEL)=Short Term Exposure Limit;

(Mppcf)=Million Particles Per Cubic Foot; (TWA)=8 HR Time Weighted Average.

=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ===========

BOILING RANGE: 241 deg F - 278 deg F SPECIFIC GRAVITY: 1.00

VAPOR DENSITY: Heavier than air. EVAPORATION RATE: Slower than ether.

COATING VOC: 4.75 lb/gl MATERIAL VOC: 4.75 lb/gl

ORGANIC SOLVENT, PERCENT BY WEIGHT: 56.800

ORGANIC SOLVENT, PERCENT BY VOLUME: 67.438

COATING DENSITY, LB/GAL: 8.356

SOLUBILITY IN WATER: Insoluble.

APPEARANCE AND ODOR: Viscous, opaque liquid with a paint thinner-like odor.

================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA =================

FLASH POINT: 61 deg F METHOD USED: TCC

FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: .9 UPPER: 8

EXTINGUISHING MEDIA: Foam, alcohol foam, CO2, dry chemical, water fog.

SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus and

full protective clothing. Keep onlookers away. Dike runoff to prevent entry

into sewers, storm drains, and watercourses. Use caution after fire is

extinguished, vapors or liquid may reignite. Notify appropriate state and local

agencies.

MATERIAL SAFETY DATA SHEET

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UNUSUAL FIRE AND EXPLOSION HAZARDS: Pressure may build up in tightly closed

containers exposed to fire which may result in rupture. Keep containers cooled

with water spray. Vapors may travel a considerable distance to a source of

ignition or collect in low areas.

======================== SECTION V - REACTIVITY DATA ==========================

STABILITY: Stable

CONDITIONS TO AVOID: Sources of ignition, poor ventilation, corrosive

atmospheres or liquids which may damage containers.

INCOMPATIBILITY (MATERIALS TO AVOID): Strong acids and bases, oxidizers.

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Carbon dioxide, carbon monoxide, and

other toxic gases.

HAZARDOUS POLYMERIZATION: Will not occur.

==================== SECTION VI - HEALTH HAZARD DATA =======================

INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Effects vary among individuals

and may include headache, dizziness, nausea, irritation of the nose, throat, and

respiratory tract, and incoordination. Severe overexposure may produce

anesthesia or unconsciousness.

SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Eye contact may

cause irritation, redness, and tearing, and blurred vision. Skin contact may

cause irritation and redness. Long term skin exposure may dry and defat the

skin, causing cracking, and in severe cases, dermatitis.

INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Ingestion can cause

gastrointestinal irritation, vomiting, nausea, and diarrhea.

HEALTH HAZARDS (ACUTE AND CHRONIC): Breathing high concentrations of aerosols or

mists of this material may cause nausea and irritation of the nose, throat, and

respiratory tract. Acute overexposure to solvent fumes during air drying of

this product may cause headache, dizziness, nausea, and loss of coordination.

Chronic overexposure to solvent fumes may cause central nervous system damage.

SIGNIFICANT DATA ON MIBK WITH POSSIBLE RELEVANCE TO HUMANS

In tests with laboratory animals, methyl isobutyl ketone produced evidence of

embryofetal toxicity at exposure levels which were toxic to mothers, but no

evidence was obtained for teratogenicity, or for embryofetal toxicity, at levels

which did not affect the mothers. Results from five mutagenicity assays with

different genetic endpoints indicate that methyl isobutyl ketone does not

produce activity typical of that of chemical mutagens. Additional studies have

shown that methyl isobutyl ketone is toxic if aspirated. It is known to enhance

the neurotoxicity of linear 6 carbon solvents.

CARCINOGENICITY: NTP: No IARC MONOGRAPHS: Yes OSHA REGULATED: No

CHRONIC EFFECTS OF ETHYLBENZENE OVEREXPOSURE

The International Agency for Research on Cancer (IARC) has evaluated

ethylbenzene (a component of xylol) and classified it as a possible human

carcinogen (Group 2B) based on sufficient evidence for carcinogenicity in

experimental animals, but inadequate evidence for cancer in exposed humans.

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Overexposure to solvent

fumes may aggravate anesthesia, respiratory tract disease or pre-existing lung

disorders, nausea, and vomiting.

EMERGENCY AND FIRST AID PROCEDURES: INHALATION OVEREXPOSURE: Remove person to

fresh air, If breathing stops, apply artificial respiration and seek immediate

medical attention. NOTE: Use supplied-air respirator for rescue in enclosed

areas. EYE CONTACT: Flush with large amounts of tepid water for at least 15

minutes, get medical attention. INGESTION: Do not induce vomiting, if aspirated

material can cause chemical pneumonitis or pulmonary edema. Drink 2 glasses of

milk or water to dilute and contact physician or poison center. SKIN: Wash with

MATERIAL SAFETY DATA SHEET

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soap and water, avoid repeated contact.

=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of

ignition. Dike to prevent entry into sewers or surface waters. Recover free

liquid by shoveling into container using non-sparking tools, or add absorbent

such as sand or earth to spill and sweep up. Provide ventilation, wear a

respirator. Notify proper authorities if spill contaminates land or waterways.

WASTE DISPOSAL METHOD: Store soaked rags or absorbent material in airtight

containers to prevent spontaneous combustion of material. Absorbent materials

may emit flammable vapors. Dispose of in chemical landfill or incinerate

assuring conformity to all applicable local, state, and federal governing

regulations.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Do not expose to flame, sparks,

or other sources of ignition. Use non-sparking alloy tools and explosion-proof

equipment for handling. The need for grounding and bonding of containers in

accordance with OSHA 29 CFR 1910.106 and NFPA 77 should be assessed before

transferring product. Store inside away from extreme temperature variations.

Protect containers from physical damage. Keep containers tightly closed when

not in use. Do not inhale vapors or mists, use with adequate ventilation and

wear a respirator. Do not store with food or animal feed.

OTHER PRECAUTIONS: Do not cut, weld, grind, drill, solder, or braze on or near

containers whether full or empty. Do not reuse containers without professional

reconditioning and testing. Do not remove warning labels from containers.

===================== SECTION VIII - CONTROL MEASURES ======================

RESPIRATORY PROTECTION: Using this product in poorly ventilated areas may

require the use of a respirator. Use Mine Safety Appliance respirator #448849

with organic vapor cartridge and mist filter (or equivalent) if air monitoring

demonstrates that the concentration of listed hazardous materials exceeds the

recommended TLV's. In enclosed areas where ventilation is not used, wear a Mine

Safety Appliance #475217 pressure/demand air-supplied respirator or equivalent.

VENTILATION: Use good general mechanical ventilation and local exhaust adequate

to reduce the concentration of vapors or mists of the listed hazardous materials

to below the Threshold Limit Value(s) and the Lower Explosion Limit.

Ventilation equipment must be explosion proof.

PROTECTIVE GLOVES: Use of gloves is recommended, use chemically resistant type.

EYE PROTECTION: Use is recommended, use splash goggles or full face shields as

necessary.

OTHER PROTECTIVE CLOTHING: Use impervious apron or coveralls to prevent

contaminating street clothes which may result in prolonged exposure. The use of

head caps or helmets is recommended.

WORK AND HYGIENIC PRACTICES: Eye washes and safety showers in the workplace are

recommended. Practice good industrial hygiene when using this product: After

using this product, do not smoke or eat until washing thoroughly. Remove

saturated clothing or shoes at once and launder before reuse.

MATERIAL SAFETY DATA SHEET

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======================= SECTION IX - MISCELLANEOUS =========================

DOT INFORMATION:

UN/NA ID No.: UN 1263

DOT HAZARD CLASS: 3 (Flammable Liquid)

PACKING GROUP: II

DOT HAZARDOUS MATERIAL PROPER SHIPPING NAME: Flammable Liquid, Paint

DISCLAIMER:

The information and recommendations contained herein were believed to be

accurate at the time of preparation or obtained from sources believed to be

generally reliable. Direct testing of this product under all conceivable

conditions of use has not been done. Information given herein is given in good

faith, however Pruett-Schaffer Chemical Corporation makes no warranty concerning

its accuracy and will not be held liable for claims relating to any party's use

of or reliance on this information.