MATERIAL
SAFETY DATA SHEET
Page: 1
PRODUCT
NAME: ANSI 70 Gray Silicone Enamel
HMIS
CODES: H F R P
PRODUCT
CODE: 32-26373 2 2 0 J
================== SECTION I
- MANUFACTURER
IDENTIFICATION =================
MANUFACTURER'S
NAME: Pruett-Schaffer Chemical Co.
ADDRESS: 3327 Stafford Street
Pittsburgh PA 15204
EMERGENCY
PHONE: 1-800-633-8253 INFORMATION PHONE: 1-412-771-2000
REVISION
DATE: 08/13/02 NAME OF PREPARER: Robert P. Barry
========== SECTION II
- HAZARDOUS INGREDIENTS/SARA III
INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE
COMPONENTS CAS
NUMBER mm Hg @ TEMP Deg F PERCENT
----------------------------------------------------------------------------------------
Film
Forming Resin
Not Avail. 37.41
Aliphatic
Petroleum Hydrocarbons (Mineral Spirits) 8052-41-3 1 68 34.36
ACGIH TLV: 100ppm TWA, OSHA PEL: 100ppm
TWA
Titanium
Dioxide, inert pigment
13463-67-7 0
0 18.85
ACGIH TLV: 10 mg/m3, OSHA PEL: 15 mg/m3,
Other TLV: 10 mg TWA
Calcium
Carbonate, inert filler
471-34-1 0 0 3.23
ACGIH TLV: 10 mg/m3, OSHA PEL: 15 mg/m3,
Other TLV: 15 mg TWA
Organoclay
68911-87-5 2.49
*
Calcium Strontium Zinc Phosphosilicate
66402-68-4 0
0 1.38
OSHA PEL: None established
*
Zinc Oxide
1314-13-2 0
0 0.32
ACGIH TLV: 10 mg/m3. OSHA PEL: 10 mg/m3
TWA total dust, 5 mg/m3 respirable
Carbon
Black Pigment
1333-86-4 0
0 0.11
ACGIH TLV: 3.5 mg/m3 TWA, OSHA PEL: 3.5
mg/m3 TWA
*
Manganese metal as drier compound
7439-96-5 0
0 0.02
ACGIH TLV: 5 mg/m3, OSHA PEL: 5 mg/m3 (C)
*
Cobalt metal as drier compound
7440-48-4 0
0 0.01
ACGIH TLV: .05 mg/m3, OSHA PEL: .05 mg/m3
* Indicates toxic chemical(s) subject to the
reporting requirements of section
313
of Title III and of 40 CFR 372.
LEGEND: (C)=Ceiling limit; (S)=Skinlimit;
(STEL)=Short Term Exposure Limit;
(Mppcf)=Million
Particles Per Cubic Foot; (TWA)=8 HR Time Weighted Average.
=============== SECTION III - PHYSICAL/CHEMICAL
CHARACTERISTICS ===========
BOILING
RANGE: 315 deg F SPECIFIC
GRAVITY: 1.15
VAPOR
DENSITY: Heavier than air.
EVAPORATION RATE: Slower than ether.
COATING
VOC: 3.30 lb/gl MATERIAL VOC: 3.30 lb/gl
ORGANIC
SOLVENT, PERCENT BY WEIGHT: 34.619
ORGANIC
SOLVENT, PERCENT BY VOLUME: 50.154
COATING
DENSITY, LB/GAL: 9.542
SOLUBIBLITY
IN WATER: Insoluble.
APPEARANCE
AND ODOR: Viscous, opaque liquid with a paint thinner-like odor.
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA
=================
FLASH
POINT: 100 deg F METHOD
USED: TCC
FLAMMABLE
LIMITS IN AIR BY VOLUME- LOWER: 2.3 UPPER: 14.4
EXTINGUISHING
MEDIA: Foam, alcohol foam, CO2, dry chemical, water fog.
SPECIAL
FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus and
full
protective clothing. Keep onlookers
away. Dike runoff to prevent entry
into
sewers, storm drains, and watercourses.
Use caution after fire is
extinguished,
vapors or liquid may reignite. Notify
appropriate state and local
agencies.
MATERIAL
SAFETY DATA SHEET Page: 2
UNUSUAL
FIRE AND EXPLOSION HAZARDS: Pressure may build up in tightly closed
containers
exposed to fire which may result in rupture.
Keep containers cooled
with
water spray. Vapors may travel a
considerable distance to a source of
ignition
or collect in low areas.
========================
SECTION V - REACTIVITY DATA
==========================
STABILITY:
Stable
CONDITIONS
TO AVOID: Sources of ignition, poor ventilation, corrosive
atmospheres
or liquids which may damage containers.
INCOMPATIBILITY
(MATERIALS TO AVOID): Strong acids and bases, oxidizers.
HAZARDOUS
DECOMPOSITION OR BYPRODUCTS: Carbon dioxide, carbon monoxide, and
other
toxic gases.
HAZARDOUS
POLYMERIZATION: Will not occur.
==================== SECTION VI
- HEALTH HAZARD DATA =======================
INHALATION
HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Effects vary among individuals
and
may include headache, dizziness, nausea, irritation of the nose, throat, and
respiratory
tract, and incoordination. Severe overexposure may produce
anesthesia
or unconsciousness.
SKIN
AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Eye contact may
cause
irritation, redness, and tearing, and blurred vision. Skin contact may
cause
irritation and redness. Long term skin
exposure may dry and defat the
skin,
causing cracking, and in severe cases, dermatitis.
INGESTION
HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Ingestion can cause
gastrointestinal
irritation, vomiting, nausea, and diarrhea.
HEALTH
HAZARDS (ACUTE AND CHRONIC): Breathing high concentrations of aerosols or
mists
of this material may cause nausea and irritation of the nose, throat, and
respiratory
tract. Acute overexposure to solvent
fumes during air drying of
this
product may cause headache, dizziness, nausea, and loss of coordination.
Chronic
overexposure to solvent fumes may cause central nervous system damage.
CARCINOGENICITY: NTP: No
IARC MONOGRAPHS: Yes OSHA
REGULATED: No
CHRONIC
EFFECTS OF CARBON BLACK OVEREXPOSURE
The
carbon black component of this formula is an IARC listed Group 2B substance,
considered
by IARC to be a "Possible human carcinogen". Carbon black is not
designated
as a carcinogen by the U.S. National Toxicology Program (NTP) or the
U.S.
Occupational Safety and Health Administration (OSHA). The American
Conference
of Governmental Industrial Hygienists (ACGIH) classifies carbon black
as
A4, "Not classifiable as a human carcinogen". Carbon black is not
presently
listed
by California Proposition 65, but the California Office of Environmental
Health
Hazard Assessment (OEHHA) published on October 29, 1999 a Notice of
Intent
to List "Carbon Black (airborne particles of respirable size)" as
a
"substance
known to the State to cause cancer".
CHRONIC
EFFECTS OF COBALT OVEREXPOSURE
The
International Agency for Reasearch on Cancer (IARC) lists cobalt and cobalt
compounds
as possible human carcinogens (Group 2B), based on sufficient evidence
for
carcinogenicity in experimental animals. However, there is inadequate
evidence
of the carcinogenicity of cobalt and cobalt compounds in humans.
MEDICAL
CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Overexposure to solvent
fumes
may aggravate anesthesia, respiratory tract disease or pre-existing lung
disorders,
nausea, and vomiting.
MATERIAL
SAFETY DATA SHEET
Page: 3
EMERGENCY
AND FIRST AID PROCEDURES: INHALATION OVEREXPOSURE: Remove person to
fresh
air, If breathing stops, apply artificial respiration and seek immediate
medical
attention. NOTE: Use supplied-air
respirator for rescue in enclosed
areas. EYE CONTACT: Flush with large amounts of
tepid water for at least 15
minutes,
get medical attention. INGESTION: Do
not induce vomiting, if aspirated
material
can cause chemical pneumonitis or pulmonary edema. Drink 2 glasses of
milk
or water to dilute and contact physician or poison center. SKIN: Wash with
soap
and water, avoid repeated contact.
=========== SECTION VII
- PRECAUTIONS FOR SAFE HANDLING
AND USE ============
STEPS
TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of
ignition. Dike to prevent entry into sewers or surface
waters. Recover free
liquid
by shovelling into container using non-sparking tools, or add absorbant
such
as sand or earth to spill and sweep up.
Provide ventilation, wear a
respirator. Notify proper authorities if spill
contaminates land or waterways.
WASTE
DISPOSAL METHOD: Store soaked rags or absorbant material in airtight
containers
to prevent spontaneous combustion of material.
Dispose of in
chemical
landfill or incinerate assuring conformity to all applicable local,
state,
and federal governing regulations.
PRECAUTIONS
TO BE TAKEN IN HANDLING AND STORAGE: Do not expose to flame, sparks,
or
other sources of ignition. Use
non-sparking alloy tools and explosion-proof
equipment
for handling. The need for grounding and bonding of containers in
accordance
with OSHA 29 CFR 1910.106 and NFPA 77 should be assessed before
transferring
product. Store inside away from extreme
temperature variations.
Protect
containers from physical damage. Keep
containers tightly closed when
not
in use. Do not inhale vapors or mists,
use with adequate ventilation and
wear
a respirator. Do not store with food or
animal feed.
OTHER
PRECAUTIONS: Do not cut, weld, grind, drill, solder, or braze on or near
containers
whether full or empty. Do not reuse
containers without professional
reconditioning
and testing. Do not remove warning
labels from containers.
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY
PROTECTION: Using this product in poorly ventilated areas may
require
the use of a respirator. Use Mine
Safety Appliance respirator #448849
with
organic vapor cartridge and mist filter (or equivalent) if air monitoring
demonstrates
that the concentration of listed hazardous materials exceeds the
recommended
TLV's. In enclosed areas where
ventilation is not used, wear a Mine
Safety
Appliance #475217 pressure/demand air-supplied respirator or equivalent.
VENTILATION:
Use good general mechanical ventillation and local exhaust adequate
to
reduce the concentration of vapors or mists of the listed hazardous materials
to
below the Threshold Limit Value(s) and the Lower Explosion Limit.
PROTECTIVE
GLOVES: Use of gloves is recommended, use chemically resistant type.
EYE
PROTECTION: Use is recommended, use splash goggles or full face shields as
necessary.
OTHER
PROTECTIVE CLOTHING: Use impervious apron or coveralls to prevent
contaminating
streetclothes which may result in prolonged exposure. The use of
head
caps or helmets is recommended.
WORK
AND HYGIENIC PRACTICES: Eye washes and safety showers in the workplace are
recommended. Practice good industrial hygiene when using
this product: After
using
this product, do not smoke or eat until washing thoroughly. Remove
saturated
clothing or shoes at once and launder before reuse.
MATERIAL
SAFETY DATA SHEET
Page: 4
======================= SECTION IX
- MISCELLANEOUS =========================
DOT
INFORMATION:
UN/NA
ID No.: NA 1993
DOT
HAZARD CLASS: NONE
PACKING
GROUP: III
DOT
HAZARDOUS MATERIAL PROPER SHIPPING NAME:
Combustible Liquid, Paint
DISCLAIMER:
The
information and recommendations contained herein were believed to be
accurate
at the time of preparation or obtained from sources believed to be
generally
reliable. Direct testing of this
product under all conceivable
conditions
of use has not been done. Information given herein is given in good
faith,
however Pruett-Schaffer Chemical Corporation makes no warranty concerning
its
accuracy and will not be held liable for claims relating to any party's use
of
or reliance on this information.