MATERIAL SAFETY DATA SHEET
Page: 1
PRODUCT NAME: ANSI 70 Gray Waterbased
Paint
HMIS
CODES: H F R P
PRODUCT CODE: 24-26373Z
1 0 0 J
================== SECTION I
- MANUFACTURER
IDENTIFICATION =================
MANUFACTURER'S NAME: Pruett-Schaffer
Chemical Co.
ADDRESS: 3327 Stafford
Street Pittsburgh PA 15204
EMERGENCY PHONE: 1-800-633-8253
INFORMATION PHONE: 1-412-771-2000
REVISION DATE: 02/15/05
NAME OF PREPARER: Robert P. Barry
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III
INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP Deg F PERCENT
----------------------------------------------------------------------------------------
Water 7732-18-5 47.88
Acrylic Polymers NOT AVAIL. 0 0
35.95
OSHA PEL: None established
Feldspar, inert filler 68476-25-5
0 0 2.46
OSHA PEL: None establishd
Rheological Additive NA 0.89
Crystalline Silica as Quartz, Sand,
SiO2 14808-60-7
0 0 0.62
ACGIH TLV: 0.1 mg/m3. OSHA PEL: 0.1 mg/m3 resp.
* Ammonia 1336-21-6 448 15
C 0.21
ACGIH: 25ppm 8hrTWA. OSHA PEL: 50ppm 8hrTWA. NIOSH: 35ppm STEL 15 MIN.
Carbon Black Pigment 1333-86-4 0 0 0.09
ACGIH TLV: 3.5 mg/m3 TWA, OSHA PEL: 3.5 mg/m3 TWA
*
Indicates toxic chemical(s) subject to the reporting requirements of
section
313 of Title III and of 40 CFR 372.
LEGEND:
(C)=Ceiling limit; (S)=Skinlimit; (STEL)=Short Term Exposure Limit;
(Mppcf)=Million Particles Per Cubic Foot;
(TWA)=8 HR Time Weighted Average.
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ===========
BOILING RANGE: n/a SPECIFIC GRAVITY:
1.15
VAPOR DENSITY: Heavier than air. EVAPORATION RATE: Slower than ether.
COATING VOC: 0.04 lb/gl
MATERIAL VOC: 0.02 lb/gl
ORGANIC SOLVENT, PERCENT BY WEIGHT: 0.164
ORGANIC SOLVENT, PERCENT BY VOLUME: 0.240
COATING DENSITY, LB/GAL: 9.613
SOLUBILITY IN WATER: Completely.
APPEARANCE AND ODOR: Viscous, opaque
liquid with an ammonia-like odor.
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA
=================
FLASH POINT: Greater than 141 deg F. METHOD USED: n/a
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER:
16 UPPER: 25
EXTINGUISHING MEDIA: Foam, alcohol foam,
CO2, dry chemical, water fog.
SPECIAL FIREFIGHTING PROCEDURES: Wear
self-contained breathing apparatus and
full protective clothing. Keep onlookers away. Dike runoff to prevent entry
into sewers, storm drains, and
watercourses. Notify appropriate state
and local
agencies.
MATERIAL SAFETY DATA SHEET
Page: 2
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Pressure may build up in tightly closed
containers exposed to fire which may
result in rupture. Keep containers
cooled
with water spray.
======================== SECTION V -
REACTIVITY DATA
==========================
STABILITY: Stable
CONDITIONS TO AVOID: Excessive heat,
freezing temperatures, corrosive
atmospheres or liquids which may damage
containers.
INCOMPATIBILITY (MATERIALS TO AVOID): No
hazardous reactions are expected to
occur under normal industrial
conditions.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Carbon dioxide, carbon monoxide, and
other toxic gases including traces of
styrene and/or acrylamide monomer.
HAZARDOUS POLYMERIZATION: Will not occur.
==================== SECTION VI
- HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF
EXPOSURE: Effects vary among individuals
and may include nausea and irritation of
the nose, throat, and respiratory
tract.
SKIN AND EYE CONTACT HEALTH RISKS AND
SYMPTOMS OF EXPOSURE: Eye contact may
cause irritation, redness, and
tearing. This material is not expected
to be a
skin irritant, however, if allowed to
remain on the skin a thin film may form
which may result in irritation depending
on the method of removal.
INGESTION HEALTH RISKS AND SYMPTOMS OF
EXPOSURE: While this material has a very
low degree of toxicity, ingestion of large
amounts can cause gastrointestinal
irritation, vomiting, nausea, and
diarrhea.
HEALTH HAZARDS (ACUTE AND CHRONIC):
Breathing high concentrations of aerosols or
mists of this material may cause nausea
and irritation of the nose, throat, and
respiratory tract. NOTE: this product contains trace amounts of
residual butyl
acrylate (CAS 141-32-2, TLV = 10 ppm
ACGIH, OSHA) and styrene monomer (CAS 100-
42-5, TLV = 50 ppm ACGIH) which may be
released during processing and storage.
At these trace levels, they should present
no hazard with normal use.
CARCINOGENICITY: NTP: Yes IARC MONOGRAPHS:
Yes OSHA REGULATED: No
CHRONIC EFFECTS OF CARBON BLACK
OVEREXPOSURE
The carbon black component of this formula
is an IARC listed Group 2B substance,
considered by IARC to be a "Possible
human carcinogen". Carbon black is not
designated as a carcinogen by the U.S.
National Toxicology Program (NTP) or the
U.S. Occupational Safety and Health
Administration (OSHA). The American
Conference of Governmental Industrial
Hygienists (ACGIH) classifies carbon black
as A4, "Not classifiable as a human
carcinogen". Carbon black is not presently
listed by California Proposition 65, but
the California Office of Environmental
Health Hazard Assessment (OEHHA) published
on October 29, 1999 a Notice of
Intent to List "Carbon Black
(airborne particles of respirable size)" as a
"substance known to the State to
cause cancer".
MATERIAL SAFETY DATA SHEET
Page: 3
CHRONIC EFFECTS OF CRYSTALLINE SILICA AS
QUARTZ
The International Agency for Research on
Cancer (IARC) has evaluated crystalline
silica, inhaled as quartz, and classified
it as a confirmed human carcinogen.
The National Toxicology Program (NTP)
classifies quartz as "reasonably
anticipated to be a human
carcinogen".
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY
EXPOSURE: Respiratory symptoms
associated with pre-existing lung
disorders may be aggravated by exposure to
this material.
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION OVEREXPOSURE: Remove person to
fresh air, If breathing stops, apply
artificial respiration and seek immediate
medical attention. NOTE: Use supplied-air respirator for rescue
in enclosed
areas.
EYE CONTACT: Flush with large amounts of tepid water for at least
15
minutes, get medical attention. INGESTION: Do not induce vomiting, if
aspirated
material can cause chemical pneumonitis or
pulmonary edema. Drink 2 glasses of
milk or water to dilute and contact
physician or poison center. SKIN: Wash
with
soap and water, avoid repeated contact.
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS
RELEASED OR SPILLED: Dike to prevent entry
into sewers or surface waters. Recover free liquid by shoveling into
container,
or add absorbent such as sand or earth to
spill and sweep up. Provide
ventilation, wear a respirator. Notify proper authorities if spill
contaminates
land or waterways.
WASTE DISPOSAL METHOD: Dispose of in
chemical landfill or incinerate assuring
conformity to all applicable local, state,
and federal governing regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND
STORAGE: Do not expose to direct sun or
freezing temperatures, store inside away
from extreme temperature variations.
Protect containers from physical
damage. Keep containers tightly closed
when
not in use. Do not inhale aerosols or mists, use with adequate ventilation
and
wear a respirator. Do not store with food or animal feed.
OTHER PRECAUTIONS: Do not cut, weld,
grind, drill, solder, or braze on or near
containers whether full or empty. Do not reuse containers without professional
reconditioning and testing. Do not remove warning labels from
containers.
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY PROTECTION: Spraying this
product in poorly ventilated areas may
require the use of a respirator. Use Mine Safety Appliance respirator
#448849
with mist filter (or equivalent) if air
monitoring demonstrates that the
concentration of listed hazardous
materials carried by aerosols exceeds
recommended TLV's.
VENTILATION: Use good general mechanical
ventilation and local exhaust adequate
to reduce the concentration of aerosols or
mists carrying listed hazardous
materials to below the Threshold Limit
Value(s).
PROTECTIVE GLOVES: Use of gloves is
recommended, use chemically resistant type.
EYE PROTECTION: Use is recommended, use
splash goggles or full face shields as
necessary.
OTHER PROTECTIVE CLOTHING: Use impervious
apron or coveralls to prevent
contaminating street clothes which may
result in prolonged exposure. The use
of
head caps or helmets is recommended.
MATERIAL SAFETY DATA SHEET
Page: 4
WORK AND HYGIENIC PRACTICES: Eye washes
and safety showers in the workplace are
recommended. Practice good industrial hygiene when using this product: After
using this product, do not smoke or eat
until washing thoroughly. Remove
saturated clothing or shoes at once and
launder before reuse.
======================= SECTION IX
- MISCELLANEOUS =========================
DOT INFORMATION:
DISCLAIMER:
The information and recommendations
contained herein were believed to be
accurate at the time of preparation or
obtained from sources believed to be
generally reliable. Direct testing of this product under all conceivable
conditions of use has not been done.
Information given herein is given in good
faith, however Pruett-Schaffer Chemical
Corporation makes no warranty concerning
its accuracy and will not be held liable
for claims relating to any party's use
of or reliance on this information.