MATERIAL SAFETY DATA SHEET
Page: 1
PRODUCT NAME: Hardener Component for
18-2-A
HMIS
CODES: H F R P
PRODUCT CODE: 18-2-B
3 1 1 X
================== SECTION I
- MANUFACTURER
IDENTIFICATION =================
MANUFACTURER'S NAME: Pruett-Schaffer
Chemical Co.
ADDRESS: 3327 Stafford
Street Pittsburgh PA 15204
EMERGENCY PHONE: 1-800-633-8253
INFORMATION PHONE: 1-412-771-2000
REVISION DATE: 12/05/03
NAME OF PREPARER: Robert P. Barry
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III
INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP Deg F PERCENT
----------------------------------------------------------------------------------------
Trimethylhexamethylenediamine 25620-58-0
0 0 34.40
OSHA PEL: None established
1,2-Diaminocyclohexane 694-83-7 0
0 30.00
OSHA PEL: one established
1,6-Diaminohexane,
(Hexamethylenediamine) 124-09-4 0
0 30.00
OSHA PEL: None established
* Free phenol (as an impurity in raw
material)108-95-2 0 0
5.60
ACGIH TLV: 5 ppm TWA (S). OSHA
PEL: 5 ppm (S), STEL NOT ESTABLISHED.
*
Indicates toxic chemical(s) subject to the reporting requirements of
section
313 of Title III and of 40 CFR 372.
LEGEND:
(C)=Ceiling limit; (S)=Skinlimit; (STEL)=Short Term Exposure Limit;
(Mppcf)=Million Particles Per Cubic Foot;
(TWA)=8 HR Time Weighted Average.
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ===========
BOILING RANGE: 358 deg F - 392 deg F SPECIFIC GRAVITY: 1.01
VAPOR DENSITY: Heavier than air. EVAPORATION RATE: Slower than ether.
COATING VOC: 0.00 lb/gl
MATERIAL VOC: 0.00 lb/gl
ORGANIC SOLVENT, PERCENT BY WEIGHT: 0.000
ORGANIC SOLVENT, PERCENT BY VOLUME: 0.000
COATING DENSITY, LB/GAL: 8.369
SOLUBILITY IN WATER: Insoluble.
APPEARANCE AND ODOR: Viscous, opaque
liquid with a slight amine odor.
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA
=================
FLASH POINT: 200 deg F METHOD USED: TCC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER:
n/a UPPER: n/a
EXTINGUISHING MEDIA: Foam, alcohol foam,
CO2, dry chemical, water fog.
SPECIAL FIREFIGHTING PROCEDURES: Wear
self-contained breathing apparatus and
full protective clothing. Keep onlookers away. Dike runoff to prevent entry
into sewers, storm drains, and
watercourses. Use caution after fire
is
extinguished, vapors or liquid may
reignite. Notify appropriate state and
local
agencies.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Decomposition and combustion products may be
toxic.
======================== SECTION V -
REACTIVITY DATA ==========================
STABILITY: Stable
CONDITIONS TO AVOID: Avoid storage at high
temperatures. Sources of ignition,
MATERIAL SAFETY DATA SHEET
Page: 2
poor ventilation, corrosive atmospheres or
liquids which may damage containers.
INCOMPATIBILITY (MATERIALS TO AVOID):
Strong acids, oxidizers and reactive
organo-metallic compounds.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Carbon dioxide, carbon monoxide, and
other toxic gases.
HAZARDOUS POLYMERIZATION: Will not occur.
==================== SECTION VI
- HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF
EXPOSURE: This material is a potential
respiratory sensitizer. Effects vary among individuals and may
include
headache, dizziness, nausea, irritation of
the nose, throat, and respiratory
tract, and incoordination. Severe overexposure
may produce anesthesia or
unconsciousness.
SKIN AND EYE CONTACT HEALTH RISKS AND
SYMPTOMS OF EXPOSURE: May cause eczema or
allergic skin reaction. Long term contact has the potential for
causing
chemical burns, necrosis, and scar tissue
formation. Eye contact may cause
irritation, redness, and tearing, and
blurred vision. Skin contact may
cause
irritation and redness. Long term skin exposure may dry and defat
the skin,
causing cracking, and in severe cases,
dermatitis.
INGESTION HEALTH RISKS AND SYMPTOMS OF
EXPOSURE: Ingestion can cause
gastrointestinal irritation, vomiting,
nausea, and diarrhea.
HEALTH HAZARDS (ACUTE AND CHRONIC):
Repeated or prolonged contact with skin may
cause eczema, dermatitis, sensitization,
or allergic skin reactions. CORROSIVE!
May cause chemical burns to eyes and
skin.
CARCINOGENICITY: NTP: No IARC MONOGRAPHS:
No OSHA REGULATED: No
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY
EXPOSURE: May aggravate pre-existing
skin conditions such as eczema,
dermatitis, or cause allergic response.
Overexposure to solvent fumes may
aggravate anesthesia, respiratory tract
disease or pre-existing lung disorders,
nausea, and vomiting.
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION OVEREXPOSURE: Remove person to
fresh air, If breathing stops, apply
artificial respiration and seek immediate
medical attention. NOTE: Use supplied-air respirator for rescue
in enclosed
areas.
EYE CONTACT: Flush with large amounts of tepid water for at least
15
minutes, get medical attention. INGESTION: Do not induce vomiting, if
aspirated
material can cause chemical pneumonitis or
pulmonary edema. Drink 2 glasses of
milk or water to dilute and contact
physician or poison center. SKIN: Wash
with
soap and water, avoid repeated
contact.
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS
RELEASED OR SPILLED: Dike to prevent entry
into sewers or surface waters. Recover free liquid by shoveling into
container,
or add absorbant such as sand or earth to
spill and sweep up. Provide
ventilation, wear a respirator. Notify proper authorities if spill
contaminates
land or waterways.
WASTE DISPOSAL METHOD: Dispose of in
chemical landfill or incinerate assuring
conformity to all applicable local, state,
and federal governing regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND
STORAGE: Do not expose to direct sun or
freezing temperatures, store inside away
from extreme temperature variations.
Protect containers from physical
damage. Keep containers tightly closed
when
not in use. Do not inhale vapors or mists, use with adequate ventilation
and
wear a respirator. Do not store with food or animal feed.
MATERIAL SAFETY DATA SHEET
Page: 3
OTHER PRECAUTIONS: Do not cut, weld,
grind, drill, solder, or braze on or near
containers whether full or empty. Do not reuse containers without professional
reconditioning and testing. Do not remove warning labels from
containers.
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY PROTECTION: Using this product
in poorly ventilated areas may
require the use of a respirator. Use Mine Safety Appliance respirator
#448849
with organic vapor cartridge and mist
filter (or equivalent) if air monitoring
demonstrates that the concentration of
listed hazardous materials exceeds the
recommended TLV's. In enclosed areas where ventilation is not
used, wear a Mine
Safety Appliance #475217 pressure/demand
air-supplied respirator or equivalent.
VENTILATION: Use good general mechanical
ventilation and local exhaust adequate
to reduce the concentration of vapors or
mists of the listed hazardous materials
to below the Threshold Limit Value(s) and
the Lower Explosion Limit.
Ventilation equipment must be explosion
proof.
PROTECTIVE GLOVES: Use of gloves is
recommended, use chemically resistant type.
EYE PROTECTION: Use is recommended, use
splash goggles or full face shields as
necessary.
OTHER PROTECTIVE CLOTHING: Use impervious
apron or coveralls to prevent
contaminating street clothes which may
result in prolonged exposure. The use
of
head caps or helmets is recommended.
WORK AND HYGIENIC PRACTICES: Eye washes
and safety showers in the workplace are
recommended. Practice good industrial hygiene when using this product: After
using this product, do not smoke or eat
until washing thoroughly. Remove
saturated clothing or shoes at once and
launder before reuse.
======================= SECTION IX
- MISCELLANEOUS =========================
DOT INFORMATION:
DISCLAIMER:
The information and recommendations
contained herein were believed to be
accurate at the time of preparation or
obtained from sources believed to be
generally reliable. Direct testing of this product under all
conceivable
conditions of use has not been done.
Information given herein is given in good
faith, however Pruett-Schaffer Chemical Corporation
makes no warranty concerning
its accuracy and will not be held liable
for claims relating to any party's use
of or reliance on this information.